Zur direkten ma?analytischen Bestimmung von Carbamaten als sehr schwache S?uren

Zusammenfassung Eine direkte maßanalytische Methode zur Bestimmung diverser Carbamate wird beschrieben. Die potentiometrische Titration mit käuflicher Tetra-n-butylammoniumhydroxid-Lösung, verdünnt mit Propanol-(2), ist bequem durchzuführen, und die erhaltenen Titrationskurven gestatten eine korrekte Auswertung.

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Direct volumetric determination of carbamates as very weak acids

Summary A volumetric procedure for the determination of some carbamates is described. The potentiometric titration with commercial tetra-n-butylammonium hydroxide solution diluted with propanol-(2) is convenient and the obtained titration curves permit a correct calculation.

     

Contact phase modulation method for acoustic nonlinear parameter measurement in solid

In this work, a new method to measure in contact the nonlinearity parameter beta of solid plates is presented. A high frequency (HF) tone-burst signal of 20 MHz is inserted in the material by a contact-transducer (with a suitable coupling). A low frequency (LF) pulse (2.5 MHz) is applied to the other face, in the opposite direction, so that the nonlinear interaction of the two waves takes place during the back propagation toward the HF transducer. This collinear interaction creates a phase modulation of the HF tone-burst which is proportional to the beta coefficient and the particle velocity of the LF wave. To determine this particle velocity, in time domain, an extended self-reciprocity calibration of the contact LF transducer is used. A numeric phase demodulation is then performed, giving the beta coefficient of the sample. The proposed method is validated by nonlinearity parameter measurements in Fused Silica. The nonlinear parameter of Fused Silica measured is found to be in good agreement with the literature, and specially the negative sign of this parameter.     

Modelling nonlinearity in piezoceramic transducers: From equations to nonlinear equivalent circuits

Quadratic nonlinear equations of a piezoelectric element under the assumptions of 1D vibration and weak nonlinearity are derived by the perturbation theory. It is shown that the nonlinear response can be represented by controlled sources that are added to the classical hexapole used to model piezoelectric ultrasonic transducers. As a consequence, equivalent electrical circuits can be used to predict the nonlinear response of a transducer taking into account the acoustic loads on the rear and front faces. A generalisation of nonlinear equivalent electrical circuits to cases including passive layers and propagation media is then proposed. Experimental results, in terms of second harmonic generation, on a coupled resonator are compared to theoretical calculations from the proposed model.     

Raman spectroscopy with an integrated arrayed-waveguide grating

An integrated arrayed-waveguide grating fabricated in silicon-oxynitride technology is applied to Raman spectroscopy. After its validation by reproducing the well-known spectrum of cyclohexane, polarized Raman spectra are measured of extracted human teeth containing localized initial carious lesions. Excellent agreement is obtained between the spectra of healthy and carious tooth enamel measured with our integrated device and spectra recorded using a conventional Raman spectrometer. Our results represent a step toward the realization of compact, hand-held, integrated spectrometers, e.g. for the detection of dental caries at an early stage.     

Laurane-derived sesquiterpenes from the marine red alga Laurencia tristicha (Rhodomelaceae)

Two new stereoisomers of laurane-derived brominated sesquiterpenes, 4-bromolaur-11-en-1,10alpha-diol (1) and 4-bromolaur-11-en-1,10beta-diol (2), one new natural product, laur-11-en-1,10alpha-diol (3), together with 11 known compounds (4-14) were isolated and identified from the organic extract of the marine red alga Laurencia tristicha. Their structures and relative stereochemistry were established by analysis of mass and NMR spectroscopic techniques.     

Fiber-optics implementation of the Deutsch-Jozsa and Bernstein-Vazirani quantum algorithms with three qubits

We report on a fiber-optics implementation of the Deutsch-Jozsa and Bernstein-Vazirani quantum algorithms for 8-point functions. The measured visibility of the 8-path interferometer is about 97.5%. Potential applications of our setup to quantum communication or cryptographic protocols using several qubits are discussed.     

Experimental error filtration for quantum communication over highly noisy channels

Error filtration is a method for encoding the quantum state of a single particle into a higher dimensional Hilbert space in such a way that it becomes less sensitive to noise. We have realized a fiber optics demonstration of this method and illustrated its potentialities by carrying out the optical part of a quantum key distribution scheme over a line whose phase noise is too high for a standard implementation of BB84 to be secure. By filtering out the noise, a bit error rate of 15.3% +/- 0.1%, which is beyond the security limit, can be reduced to 10.6% +/- 0.1%, thereby guaranteeing the cryptographic security.     

Apatite-structure crystal, Yb(3+):SrY(4)(SiO(4))(3)O, for the development of diode-pumped femtosecond lasers

We report what is believed to be the first diode-pumped Yb(3+): SrY(4)(SiO(4)) (3)O laser. We investigate both the cw and the mode-locked regimes. In the cw regime an average output power of 1.05 W is demonstrated for 3.6 W of incident pump power. In the femtosecond regime a pulse duration of 94 fs for an average power of 110 mW is obtained at a central wavelength of 1068 nm. This is, to our knowledge, the first femtosecond mode-locked oscillator made with an Yb-doped apatitelike crystal. These properties are related to the unique spectroscopic properties of Yb(3+) ions in this atypical apatite-family crystal.     

Interactions of particles and microbubbles with turbulence

Dilute, dispersed two-phase flows arise in many contexts ranging from solid particles or droplets in gas flows to bubbles in liquids. Many of the flows of interest are turbulent, which presents a complex problem to analyze or to determine the dominant physical processes contributing to the observed phenomena. Advances in experimental techniques have made it possible to measure directly turbulent and particle velocity fluctuations in dilute systems. This has provided a counterpart to advances in computational and analytical models and a basis on which to test these models. Three specific areas are considered: the fluctuating forces on an individual particle in an unsteady flow, the response of a solid particle to a turbulent air flow, and the corresponding response of a small bubble in turbulent liquid flows. Results from direct numerical simulations are presented for each of these, including the nonuniform distribution of particles generated by local instantaneous features of the flow. The issue of turbulence modulation at low to moderate void fractions is discussed.